Do you have questions? Let's talk! Get in Contact
info@betakim.com.tr

Indium Chloride Anhydrous, Indium Trichloride, 10025-82-8

Indium Chloride Anhydrous, Indium Trichloride, 10025-82-8

INDIUM CHLORIDE ANHYDROUS (INCL₃)
INDIUM CHLORIDE ANHYDROUS / INDIUM TRICHLORIDE / INDIUM(III) CHLORIDE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Indium Chloride Anhydrous
Chemical Name Indium(III) Chloride, Indium Trichloride
Other Names InCl₃
CAS Number 10025-82-8
EC Number (EINECS) 233-043-0
Chemical Formula InCl₃
Molecular Weight 221.18 g/mol
Appearance White to yellow crystalline solid
Odor Odorless
Physical State (20°C) Solid (crystalline)

2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Indium chloride is an inorganic compound of indium and chlorine. Indium ions (In³⁺) and chloride ions (Cl⁻) are present in a 1:3 ratio. It appears as a white to yellow crystalline solid. It exhibits high solubility in water and hydrochloric acid. Due to its hygroscopic nature, it is sensitive to degradation in humid environments. It is an important precursor for indium-based semiconductors.

Structural Features:

                    INDIUM CHLORIDE ANHYDROUS [InCl₃]
                          |
                In³⁺ - Cl⁻ Ionic/Covalent Bonds
                          |
        +----------------+----------------+
        |                |                |
    Crystalline        Soluble in        Highly
    Structure          Water and         Hygroscopic
                       Acids

2.2. Structural Properties

Parameter Value
Crystal Structure Monoclinic
Chemical Formula InCl₃
Molecular Weight 221.18 g/mol
Density ~3.46 g/cm³ (25°C)
Appearance White to yellow crystalline solid
Melting Point ~586 °C
Boiling Point ~800 °C (decomposes)
pH (1M solution) Slightly acidic (~4.0-5.0)

3. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Description
Appearance White to yellow crystalline solid -
Odor Odorless -
Chemical Formula InCl₃ -
Molecular Weight 221.18 g/mol -
Density ~3.46 g/cm³ -
Melting Point ~586 °C -
Boiling Point ~800 °C Decomposes
Solubility in Water (25°C) High solubility -
Solubility in Hydrochloric Acid High solubility -
Solubility in Alcohol Soluble -
pH (1M solution) Slightly acidic (~4.0-5.0) -
Stability Hygroscopic Must be stored in moisture-free conditions
Hygroscopicity High Absorbs moisture from air

4. PURITY GRADES

Parameter Technical Grade High Purity Grade Analytical Grade
Purity (InCl₃) ≥ 99.0% ≥ 99.5% ≥ 99.9%
Indium (In) Content ≥ 52.0% ≥ 52.5% ≥ 52.8%
Chloride (Cl⁻) Content ≥ 47.5% ≥ 48.0% ≥ 48.3%
Iron (Fe) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm
Lead (Pb) ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Zinc (Zn) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm
Calcium (Ca) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm
Sodium (Na) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm
Sulfate (SO₄²⁻) ≤ 0.5% ≤ 0.2% ≤ 0.1%
Moisture / Loss on Drying ≤ 0.5% ≤ 0.2% ≤ 0.1%
Particle Size Variable Variable Variable

5. STABILITY AND REACTIVITY

Parameter Information
Chemical Stability Hygroscopic; stable under dry, closed conditions.
Conditions to Avoid High humidity, exposure to open atmosphere, prolonged air contact, high temperatures.
Incompatible Materials Strong oxidizing agents, strong acids, alkali metals.
Hazardous Decomposition Products At high temperatures: hydrogen chloride (HCl) and indium oxide (In₂O₃).
Hazardous Polymerization Will not occur.
Hygroscopicity High; when exposed to air, it absorbs moisture and tends to deliquesce (become liquid).

5.1. Chemical Reactions

  • Hydrolysis (with Water):
    InCl₃ + 3H₂O → In(OH)₃↓ + 3HCl
    InCl₃ + 3H₂O → In₂O₃ + 6HCl (at high temperature)

  • Behavior in Aqueous Solution:
    InCl₃(aq) → In³⁺(aq) + 3Cl⁻(aq)

  • Reaction with Bases:
    InCl₃ + 3NaOH → In(OH)₃↓ + 3NaCl
    InCl₃ + 4NaOH → Na[In(OH)₄] + 3NaCl (excess base)

  • Reaction with Ammonia:
    InCl₃ + 3NH₃ + 3H₂O → In(OH)₃↓ + 3NH₄Cl

6. APPLICATION AREAS
6.1. Semiconductor and Electronic Materials

Application Function Details
Indium-Based Semiconductors Precursor InP, InAs, InSb production
Optoelectronic Materials Additive Indium-based optical materials
Thin Film Coatings Source material PVD and CVD applications
ITO (Indium Tin Oxide) Precursor Transparent conductive oxide production

6.2. Catalyst Applications

Application Function Details
Lewis Acid Catalyst Catalytic activity Friedel-Crafts reactions
Organic Synthesis Catalyst Catalytic activity Various organic transformations
Polymerization Catalyst Polymerization initiator Some polymerization reactions

6.3. Advanced Materials and Nanotechnology

Application Function Details
Nanomaterial Synthesis Starting material Indium-based nanoparticles
Materials Science Research Source material New material development
Quantum Dots Precursor Indium-based quantum dots

6.4. Sectoral Suitability Table

Sector Suitability Explanation
Electronics Suitable Semiconductor materials, InP, InAs, ITO
Optoelectronics Suitable Optical materials, thin film coatings
Catalyst Suitable Lewis acid, organic synthesis
Nanotechnology Suitable Nanoparticle synthesis, quantum dots
Research Suitable Materials science, advanced material development
Pharmaceutical Not Suitable Not suitable
Agriculture Not Suitable Not suitable
Food Not Suitable Not suitable

7. PRODUCTION PROCESS

Stage Process Description
1. Raw Material Preparation Indium metal (In) or indium oxide (In₂O₃) High purity indium sources
2. Chlorination / Dissolution Reaction with chlorine gas or hydrochloric acid 2In + 3Cl₂ → 2InCl₃ or In₂O₃ + 6HCl → 2InCl₃ + 3H₂O
3. Purification Sublimation/distillation Removal of impurities
4. Crystallization Controlled cooling Obtaining pure crystalline form
5. Drying Controlled conditions Removal of moisture
6. Packaging Moisture-proof packaging Packaged under inert atmosphere due to hygroscopic nature

7.1. Major Producing Countries

Country Description
China Major producer
USA Indium production (Sigma-Aldrich, American Elements)
Germany High purity production (Alfa Aesar)
Japan High purity production

8. ALTERNATIVE / SUBSTITUTE PRODUCTS

Alternative Description When to Use
Indium(I) Chloride (InCl) Less stable, special applications When +1 oxidation state is required
Gallium Chloride (GaCl₃) Similar semiconductor applications When Ga is required
Indium Oxide (In₂O₃) Indium source When oxide form is required
Indium Nitrate (In(NO₃)₃) Indium source When different anion is required
Indium Acetate (In(CH₃COO)₃) Organic synthesis When organic solvent compatibility is required

9. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) ~2,000 mg/kg (low toxicity)
Dermal Toxicity Low
Skin Irritation Mild to moderate irritant
Eye Irritation Serious irritant
Inhalation Dust inhalation may cause respiratory tract irritation.
Carcinogenicity Not classified as carcinogenic.
Mutagenicity Not mutagenic.
Chronic Effects Rare element compounds have low bioavailability; prolonged exposure may cause lung effects.
Environmental Hazards Moderate aquatic toxicity.

9.1. GHS Classification

Hazard Class Category H-Statement
Skin Irritation Category 2 H315: Causes skin irritation.
Eye Irritation Category 2A H319: Causes serious eye irritation.
Specific Target Organ Toxicity Category 3 H335: May cause respiratory irritation.
Hazardous to the Aquatic Environment Category 2 H401: Toxic to aquatic life.

Signal Word: WARNING

Hazard Pictograms: GHS07 (Exclamation Mark)

10. PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust.
P264 Wash thoroughly after handling.
P271 Use only in well-ventilated areas.
P280 Wear protective gloves/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do.
P337+P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container in accordance with local regulations.

11. FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Remove to fresh air. If symptoms persist, seek medical attention.
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical attention.
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention.
Ingestion Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention.

12. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store in a cool, dry, and well-ventilated area. Ensure a moisture-free environment.
Container Requirements Airtight, moisture-proof containers. Glass bottle or under inert atmosphere.
Temperature Room temperature (15-25°C).
Shelf Life 12-18 months under appropriate conditions (due to hygroscopic nature).
Stability Note Highly hygroscopic; rapidly degrades in humid environments. Must be stored in closed packaging under inert atmosphere.

13. PACKAGING OPTIONS

Packaging Type Quantity Material
Laboratory Packaging 5 g, 10 g, 25 g, 50 g Sealed glass bottle, ampoule, inert atmosphere
Laboratory Packaging 100 g, 500 g HDPE bottle, inert atmosphere
Industrial Packaging 1 kg, 5 kg PE-lined drum, moisture-proof
Industrial Packaging 25 kg HDPE drum, moisture-proof

14. TRANSPORT INFORMATION

Parameter Information
UN Number Not classified (specific regulations apply for metal compounds)
Hazard Class -
Packing Group -
ADR/RID Not regulated
IMDG Not regulated
IATA Not regulated
HS Code 2827.39.00.00.00 (Other chlorides)

15. REGULATORY STATUS

Region / Authority Status
European Union (REACH) Registered
Turkey (KKDIK) Compliance required
TSCA (USA) Registered
CLP/GHS Compliant
FDA/EFSA Not approved as a food additive
ISO 9001:2015 Production compliance

16. OTHER NAMES AND SYNONYMS

Name Description
Indium Trichloride Chemical name
Indium(III) Chloride Chemical name
InCl₃ Chemical abbreviation
Indium Chloride Anhydrous English name
Indium Trichloride English name

17. QUICK REFERENCE TABLE

Property Value
CAS Number 10025-82-8
EC Number 233-043-0
Chemical Formula InCl₃
Molecular Weight 221.18 g/mol
Appearance White to yellow crystalline solid
Density ~3.46 g/cm³
Melting Point ~586 °C
Solubility in Water High solubility
HS Code 2827.39.00.00.00
GHS Signal Word WARNING

18. CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • Highly Hygroscopic Nature: Indium chloride anhydrous has a very high moisture absorption capacity. When exposed to air, it rapidly absorbs moisture, begins to dissolve, and loses its quality. Extreme care must be taken to avoid moisture during storage and handling.

  • Thermal Decomposition: At high temperatures, toxic hydrogen chloride (HCl) gas is released. Ventilation is essential.

  • Incompatibility: Contact with strong oxidizing agents creates a fire and explosion risk.

  • Eye and Skin Irritation: Due to its acidic nature, it causes irritation to skin and eyes. Protective equipment is mandatory during use.

  • Critical Raw Material: Indium is a critical and valuable metal for ITO and semiconductor applications; losses should be minimized and recycling options explored.

BEST PRACTICE RECOMMENDATIONS:

  • Storage:

    • Store in a cool, dry, and well-ventilated area.

    • Use moisture-proof, airtight containers.

    • Keep away from oxidizing agents.

    • Store at room temperature (15-25°C).

  • Handling:

    • Immediately close containers tightly when not in use.

    • Ensure a dry working environment during use (humidity control).

    • Use a dust mask (N95 or better), protective goggles, and chemically resistant gloves.

    • Avoid dust formation and inhalation.

    • Wash hands thoroughly after handling.

    • When preparing solutions, add slowly due to acidic character.

  • Waste Management:

    • Dispose of in accordance with local regulations as heavy metal waste.

    • Do not discharge into water sources or sewers.

    • For large quantities, indium recovery should be considered (valuable and critical metal).

LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Indium chloride anhydrous requires careful handling and storage due to its highly hygroscopic nature and critical role in electronic applications; it is an important raw material for semiconductor, ITO, and catalyst applications.

Images

Do you have questions? Let us help!

Effective Business Solutions? — Get in Contact
Scroll