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Ludigol, Sodium Nitro Benzene Sulfonate, Ludigol F, 127-68-4

Ludigol, Sodium Nitro Benzene Sulfonate, Ludigol F, 127-68-4

Ludigol (Sodium 3-Nitrobenzenesulfonate)

Basic Information

  • Chemical Name: Sodium 3-nitrobenzenesulfonate

  • CAS No: 127-68-4

  • Molecular Formula: C6H4NO5S.Na

  • Molecular Weight: 225–226 g/mol

  • Appearance: White or pale yellow crystalline powder

  • Solubility: Soluble in water

  • Density: ~1.48 g/cm³

  • Odor: Mild, characteristic

Synonyms / Trade Names

  • Ludigol F (BASF)

  • NACAN

  • NITROL S

  • Resist Salt / Resist S

  • Sodium 3-nitrobenzenesulfonate

  • 3-Nitrobenzenesulfonic acid sodium salt

  • Ludigol 75%, Ludigol 96%

Chemical Properties

  • Function: Mild oxidizing agent, anti-reducing agent

  • Role: Prevents reduction of dyes, enhances color brightness

  • Granules: Dust-free form available

Applications

  • Textile Industry:

    • Prevents reduction of reactive and disperse dyes during steaming

    • Used in re-oxidation of vat dyes

    • Essential for monochlorotriazine dyes (Procion H type)

    • Improves brightness in dark shades and silk dyeing

  • Industrial Uses:

    • Auxiliary agent in electronics, photography, and coating industries

    • Brightness enhancer in electroplating baths

  • Laboratory Use:

    • Reagent in synthesis of azetidinyl ketolides (antibiotic intermediates)

Alternatives

Alternative Product Description Application
Sodium Nitrite (NaNO₂) Mild oxidizer Anti-reducing agent in textile dyeing
Sodium Perborate Oxidizer, bleaching agent Color fixation in reactive dyes
Sodium Persulfate (Na₂S₂O₈) Strong oxidizer Post-printing and dye fixation
Resist Salt / Resist S Commercial equivalent Anti-reducing agent in reactive dyes
Ludigol F / Ludigol KN BASF variants Steam fixation, dark shade protection
Nitrol S / Nacan / Tiskan Same chemical structure Marketed under different brands

Usage

  • Typical dosage: 10 g/kg

  • Purpose:

    • Prevents dye solution degradation

    • Keeps dye solutions fresh for longer

    • Ensures sharper edges in printed fabrics

    • Enhances brightness and stability, especially in dark tones and silk

Ludigol – Sectoral Suitability Table

Sector Application Benefit / Function
Textile Reactive & disperse dyeing, steaming, vat dye re-oxidation Prevents dye reduction, enhances brightness, sharper print edges, essential for Procion H dyes
Silk & Dark Shades Dye fixation during steaming Maintains deep tones, prevents dullness, improves color vibrancy
Leather Dyeing and finishing processes Stabilizes colors, prevents fading during curing
Paper Dyeing and coating Improves color fastness and brightness
Electronics Electroplating baths Acts as brightness enhancer, stabilizes bath chemistry
Photography Auxiliary chemical in developing processes Controls reduction reactions, improves image clarity
Coatings Industrial coatings and paints Ensures uniform color fixation, prevents unwanted reduction
Laboratory / Pharma Intermediate in synthesis (e.g., azetidinyl ketolides) Functions as a reagent in advanced chemical synthesis

Key Notes:

  • Dosage: Typically 10 g/kg in textile applications.

  • Critical Use: Required for monochlorotriazine dyes (Procion H type) during steaming.

  • Optional Use: For dichlorotriazine (Procion MX) and monofluorotriazine (Cibacron F) dyes, beneficial but not strictly necessary.

  • Alternatives: Sodium nitrite, sodium perborate, sodium persulfate, Resist Salt/S, Ludigol F/KN (BASF variants).

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